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1-Fluoro-3,3-dimethylbenziodoxole

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  • IUPAC Name: 1-Fluoro-3,3-dimethyl-1,3-dihydro-1λ3-benzo[d][1,2]iodaoxole
  • Synonyms: Alcohol fluoroiodane
  • CAS: 1391728-13-4
  • Smiles: CC(OI1C(F)(F)C(F)(F)F)(C)C2=C1C=CC=C2
  • Chemical formula: C9H10FIO
  • Molecular weight: 280.08
  • Purity: 95%+

1-Fluoro-3,3-dimethylbenziodoxole is a crystalline, off-white solid which can be handled under air for extended periods without noticeable hydrolytic decomposition. It can act as a good acceptor of Ruppert-Prakash reagent to generate Alcohol-CF3-reagent (Togni Reagent I). Speaking about its synthetic utility, it has been shown that in the presence of excess fluoride ions (provided by triethylamine-hydrogen fluoride complexes), it can effectively function as an electrophilic fluorination reagent for easily enolizable diketo substrates.

 

Download the MSDS.