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Phenylsulfanyltetrafluoroethyl trimethylsilane

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  • IUPAC Name: trimethyl(1,1,2,2-tetrafluoro-2-(phenylthio)ethyl)silane
  • Synonyms: PhSCF2CF2TMS
  • CAS: 1000293-91-3
  • Smiles: FC(F)(SC1=CC=CC=C1)C(F)(F)[Si](C)(C)C
  • Chemical formula: C11H14F4SSi
  • Molecular weight: 282,37
  • Purity: 95%+

Phenylsulfanyltetrafluoroethyl trimethylsilane acts as nucleophilic phenylsulfanyltetrafluoroethylation reagent. A phenylsulfanyltetrafluoroethyl moiety incorporated in the substrate can be treated with tributyltin hydride and generate the corresponding fluoroalkyl radical. If the substrate lacks any olefine, it can be reduced to tetrafluoroethyl group.